Abstract

Two commercial polyesters, a virgin (VPET) and a recycled (RPET), were mechanically recycled in a closed loop with a pilot recycling line designed for bottle-to-bottle recycling. The stretchability after one, two and four loops were measured by uni-axial drawing experiments above the glass transition temperatures of the polymers. Thanks to the time-temperature equivalence principle, the materials were deformed in a physical state equivalent to the one encountered during the injection stretch-blow molding (ISBM) process. The mechanical recycling of the commercial VPET leads to a significant loss of drawability. The lower drawability of RPETs (commercial or produced by the pilot line) could explain the more numerous bottles explosions during ISBM. A microstructural interpretation is proposed through SEC chromatography and DSC analysis.

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