Abstract
The behavior of tritium in and released from Li-Al alloys was examined by dissolving irradiated alloys in a NaOH solution or by heating them. In the alloys with a higher Li concentration, tritium was concentrated in the β phase. A part of the tritium was detected as molecular forms, HT and T 2, which themselves were precipitated in the alloys. The temperature of the tritium-release peak increases with increasing concentration of Li in the alloys. This was explained by the retardation of tritium diffusivity due to the chemical interaction with Li.
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