Abstract
exciplex. Enhancement in the MFEs in polar solvent is attributable to the stability of the RIP over the exciplex in the polar solvents. The remarkable influence of chain lengths on the MFEs was discussed in connection with the edge-to-edge distances, 〈r〉, of the two radicals, which were obtained by molecular dynamics calculations. The influence of temperature was also discussed. In the present paper, we report the effects of high magnetic field (e13 T) on the exciplex fluorescence intensities and lifetimes of Phen-n-O-2-DMA in N,N-dimethylformamide by means of photostationary and laser-induced fluorescence. The reversal of the effects occurs in the magnetic field above 1 T and is interpreted in terms of the ¢g mechanism of the radical pair model. Experimental Section
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