Abstract
Effects of Ca and Zr substitution upon the dielectric properties of Ba 5LaTi 3Ta 7O 30 ceramics were investigated together with the structural characterization. All the samples of Ba 5La(Zr x Ti 1− x ) 3Ta 7O 30 formed a filled tungsten–bronze structures, whereas the solid solution limit was determined as x=0.25 in (Ca x Ba 1− x ) 5LaTi 3Ta 7O 30. Beyond this limit secondary phase of CaTa 2O 6 was detected and it would become the major phase for the Ca-rich compositions. The temperature coefficient of dielectric constant was improved with increasing Zr content while the dielectric constant decreased and the low dielectric loss varied little (in the order of 10 −4). In the case of (Ca x Ba 1− x ) 5LaTi 3Ta 7O 30, small temperature coefficient of dielectric constant could be obtained with increasing Ca content while the dielectric constant decreased significantly, and a small amount substitution of Ca for Ba induced decrease in dielectric loss.
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