Abstract

The effects of ageing at 773K for 3h on microstructure and superelastic behavior in B2-B19' thermoelastic martensitic transformations of Ni45.3Ti29.7Hf20Pd5 (аt%) single crystals were investigated in this study. Ageing introduced nanoscale H and H′ phase precipitates, which resulted in a decrease of B2-B19' transformation temperatures, a dispersion hardening of the B2 phase and a twofold increase in the superelasticity range (up to ΔТSE=200K) as compared with quenched crystals. In aged single crystals, reversible thermoelastic transformations with an extremely high critical stress level (σcr=1500MPa) and reversible strain up to 1.8% were obtained at elevated temperatures (450K).

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