Abstract

Abstract In this paper, crystal structure, porosity, bond characteristics, Raman spectra and microwave dielectric properties of Li3Mg2-xZnxSbO6 ceramics were investigated. The phase information of salt structure was determined via X-ray diffraction and Rietveld refinement. The dielectric constant and loss of the ceramic under complete densification were obtained by excluding the porosity. Based on P-V-L theoretical calculation, the relationship among bond ionicity, lattice energy, bond energy and microwave dielectric properties was established. Raman spectroscopy analysis shows the vibration of the Bg mode plays a key role in dielectric loss. Excellent microwave dielectric properties at x = 0.02 can be obtained (er = 8.57, Q × f = 106617 GHz, τf = −9.8 ppm/°C).

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