Abstract
Titration calorimetric and densimetric measurements have been applied to study the selective interactions of two disaccharides composed of two glucose units, maltose and cellobiose, with 15-crown-5 and 18-crown-6 in dilute aqueous solutions. Maltose and cellobiose form thermodynamically stable complexes with different stoichiometries with 18-crown-6 but not with 15-crown-5. The obtained results are explained by the different states of the disaccharides in aqueous solution due to effect of the type of linkage between glucose units
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