Abstract
The morphology of ADMET-synthesized polyethylene with n-butyl branches precisely spaced on every 39th carbon (EH39) was studied in comparison with an ethylene/1-hexene addition copolymer possessing the same branching probability, the goal being to elucidate the effect of the intramolecular sequence length heterogeneity on the lamella crystal thickness and its distribution. EH39 was found to have an orthorhombic crystalline polymorphism, which is normal for commercialized polyethylenes and different from that of the other ADMET polyethylenes with shorter CH2 spacing (C15, C21). EH39 exhibits a narrow lamella thickness distribution; the average thickness (lc,av.) corresponds exactly to the space length between two consecutive branches, suggesting the complete exclusion of n-butyl branches from the crystal stem. The average thickness, lc,av. mentioned above is also coincident with that obtained from WAXS and SAXS. On the other hand, the 1-hexene copolymer forms much thicker lamellae and a broader thickness d...
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