Abstract
The effect of the reaction medium on the kinetics and mechanism of cationic polymerization and copolymerization of cyclic ethers is considered. It is shown that a change in the conditions of solvation of reaction sites by the components of the system, leading to a substantial effect on the characteristics of the course of the process, may be achieved not only by a change in the nature of the solvent, but also by the introduction into the reaction mixture of small additions of substances that preferentially solvate the cation or anion or both the oppositely charged ends of the active site that exists as a cyclic zwitter ion pair.
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