Effect of the iron content on the thermal and dielectric relaxation process of sodium zinc-phosphate quaternary glassy systems

Abstract

To explore the consequence of Na2O substitution by Fe2O3 on the physical, thermal and dielectric properties of zinc-phosphate-based glassy systems, a series of samples with chemical compositions of 25ZnO-40P2O5-(35-x)Na2O-xFe2O3 where, (x = 0.10, 0.15, 0.20, 0.25) have been prepared by melt quenching technique. The well-known Archimedes principle is deployed to measure the value of densities of the materials. DSC thermographs specify that the glass transition temperature (Tg) declines with the incorporation of Fe2O3 content. While thermal stability increases upon adding the Fe2O3 content. The dielectric constant (ε/) and dielectric loss (ε//) rise with an increase in temperature and fall as frequency rises sharply. The obtained relaxation time exhibits Arrhenius behaviour, and the dynamic conductivity relaxation process is not of the Debye type because the Kohlrausch stretching exponent (β) value is not equal to unity. According to the scaled electric modulus (complex) spectra, composition instead of temperature affects the dynamic conductivity relaxation mechanism.