Abstract
21/4Cr-1Mo ferritic steel is generally used in the normalized and tempered condition for steam-generator tubes in fast breeder reactors. The microstructure of the alloy changes on tempering, depending on the type of carbides formed, as a function of tempering time. At the very early stage of tempering (up to ∼30 min), most of the cementite (Fe3C) dissolves, causing trapping of Cr and Mo to form their carbides. With an increase in the tempering time more Cr and Mo are used up for carbide formation. This leads to a decrease in the available Cr content, which is generally responsible for the formation of a protective oxide scale. It is thus expected that a decrease in the oxidation resistance will occur with an increase in tempering time.
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