Effect of novel graphitic carbon/NiO hole transporting electrode on the photovoltaic and optical performance of semi-transparent perovskite solar cells.

Abstract

Perovskite devices can play a critical role as tunable semi-transparent photovoltaics managing the buildings' energy health for energy harvesting, storage and utilization. Here we report ambient semi-transparent PSCs with novel graphitic carbon/NiO-based hole transporting electrodes having variable thicknesses achieving a highest efficiency of ∼14%. On the other hand, the altered thickness produced the highest average visible transparency (AVT) of the devices, nearly 35%, which also influenced other glazing-related parameters. This study envisages the impact of the electrode deposition technique on indispensable parameters like colour rendering index, correlated colour temperature, and solar factor evaluated using theoretical models to illuminate these CPSCs' colour and thermal comfort for BIPV integration. The solar factor value between 0 to 1, CRI value >80 and CCT value >4000 K make it a significant semi-transparent device. This research work suggests a possible approach to fabricating carbon-based PSC for high-performance semi-transparent solar cells.