Effects of the hydrophilic–lipophilic balance of inorganic nanoparticles on the properties of a non-aqueous drilling fluid with organo-palygorskite

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Abstract The use of nanoparticles in the composition of drilling fluids can improve some of their properties (e.g. thermal, mechanical, electrical and rheological) due to their small size and high surface area, which can diminish the loss of fluid to the formation, thereby increasing thermal conductivity, reducing friction and improving well stability. In this work, we investigated the rheological and static filtration properties and the thermal performance of non-aqueous drilling fluids with organo-palygorskite-containing hydrophobic alumina (Al2O3) and amphiphilic strontium nickelate (SrNiO3) nanoparticles in varying concentrations. The results indicate that the fluids with nanoparticles had greater plastic viscosity and lower filtrate volumes. With regard to thermal performance, the fluids with nanoparticles absorbed more heat when subjected to higher temperatures. However, this excess energy was more easily released upon cooling. This study demonstrates the affinity of nanoparticles with the solvent phase of a drilling fluid and how this interaction affects their properties, with a particular emphasis on amphiphilic nanoparticles, which have been shown to have better performance in non-aqueous fluids with organo-palygorskite.

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Investigating lost circulation in DEA 13 JIP has shown that it is difficult to arrest losses while drilling with non-aqueous drilling fluids (NAF) as compared to aqueous drilling fluids (AF). In an earlier work (Kulkarni 2012), a novel method was discussed to characterize the plugging (of LCM particles and Fibers) performance of non-aqueous and aqueous drilling fluids using viscoelastic parameters under shear stress (First Normal Stress Difference=N1). This paper discusses the modification of drilling fluids (particularly non-aqueous fluids) to combat lost circulation. N1 measured at low and moderate shear stresses for different aqueous and non-aqueous drilling fluids shows that the magnitude of N1 for AF was significantly higher than that for NAF; although, the FANN® 35 viscometer shear rheology of both was similar. Another important finding was that adding certain polar-organic compounds to the NAF improves its N1 magnitude remarkably, which in turn was found to improve the drilling fluid's performance in lost circulation applications. For representative AF and NAFs, with the same FANN 35 viscometer rheology properties and lost circulation materials, fracture plugging efficiency was probed on a Permeability Plugging Apparatus (PPA) using a tapered slot. The plugging performance of the LCM in the AF was significantly better than in the NAF for the same combination of LCM. This difference in plugging performance was attributed to the noticeable difference in N1 observed for these two drilling fluids. The relation between N1 and plugging efficiency became evident when the addition of polar-organic compounds to the NAF increased its N1 and improved its plugging efficiency. These findings could be used to tailor the NAF for LCM treatment during the mud design phase and help alleviate trial-and-error in the LCM design.

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Evaluation of polymer/bentonite synergy on the properties of aqueous drilling fluids for high-temperature and high-pressure oil wells
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Drilling fluids are tested daily with many properties recorded to ensure that drilling operations are performed with the highest possible efficiency and in compliance with operator requirements. Mud check data are accumulated over the years but is heavily underutilised, as it is rarely used after the job is finished; this data are instrumental for optimization of future drilling fluids, however.The original global daily mud check data for ~30,000 wells (>780,000 individual checks) since 2016 is retrieved from the service company mud database. This large volume of data is prepared by selecting the key drilling parameters and fluid properties and performing the extensive cleaning to enable the usability of the data. It becomes evident that to make fluid profiling meaningful, just focusing on fluids properties is not enough, but the associated drilling parameters and conditions are critical for a meaningful analysis. The dataset is then evaluated using exploration data analyses and multidimensional statistical analysis techniques. An evolving barrel cost is calculated from product concentrations and product costs, which is then used to calculate the cost of dilution. This is combined with the costs of fluid treatment, circulation, and tripping to create a normalised cost of fluid use. By possessing a normalised cost of fluid use, a holistic cost model can be created an applied to future wells to better inform decisions on fluid selection.The clean dataset is comprised of more than 425,000 records with drilling parameters such as depths, hole size, bottomhole circulating temperature, and main drilling fluid properties, some being generic (e.g., rheology at different shear rates, fluid loss, and solids contents) and some specific for the fluid type, such as water-based mud (WBM) and nonaqueous fluid (NAF). As a part of the exploratory data analyses, all the attributes are evaluated by reviewing individual distributions, running pair-wise correlations, and performing cluster analysis to identify groups of highly correlated properties. The fluid types and families are then profiled using aggregated properties (5th, 50th, and 95th percentiles) and analysed for (dis)similarity between fluid types and families. Several dimensionality reduction techniques are also tested to visualise fluid similarities and cluster fluids by a multitude of properties.The developed analytics framework enables understanding of relationships between drilling fluid parameters and associated drilling properties, determines similarity of fluid systems in terms of key properties, and defines the fluid properties that are optimal or require adjustments for a set of drilling conditions. The paper explains how fluid profiles built on large-scale historical usage data enable new applications of fluid systems. To demonstrate the power of the fluid profiling approach, the analysis is performed for different geographical locations and drilling conditions. Examples also include product family similarity evaluation across fluid types, providing a path toward potential replacement of NAFs with similarity in properties but more cost effective and environmentally benign WBMs.The data analytics framework is developed and presented here, relying on hundreds of thousands of drilling fluid check records, cleaned and processed to enable data-driven decisions on drilling fluid type and family selection, and optimal fluid property ranges—improving drilling process efficiency.

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Technology Focus: Drilling and Completion Fluids (November 2011)
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  • Brent Estes

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Successful Field Application of Organophilic Clay-Free Invert Emulsion Fluid to Protect the Reservoir Core from Drilling Fluid Damage: Case Study from a Kuwait Field
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Composition and Properties of Drilling and Completion Fluids
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Composition and Properties of Drilling and Completion Fluids

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Effect of Surfactants on the Performance of Water-Based Drilling Fluids
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Impact of Quartz/Argillaceous Sandstone and Siliceous/Kaolinitic Claystone Contamination of Drilling Fluid and Filter Cake Properties
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  • Geofluids
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The drilling fluid must be designed through a comprehensive process to select the right additives, and then must passed through different API standard evaluation processes to ensure the quality. However, the contamination of the drilling fluid with the drilled cuttings caused a significant alteration in the drilling fluid and sealing properties of the drilling fluid. Therefore, many studies have been conducted to identify the effect of different cuttings on the drilling fluid properties. The current work emphasized on the impact of four different cuttings (quartz sandstone, Argillaceous sandstone, Siliceous claystone, and Kaolinitic claystone). The utilized cuttings in this work were selected carefully from different sandstone types to have varied clay content ranged from 0 to 70%. The selected cuttings were prepared and then characterized in term of their mineral composition and particle size distribution. In order to accomplish the objective of this work, the base mud contains zero cutting concentration, after that, an additional four drilling fluid samples were prepared by adding the prepared cuttings in two different concentrations include 5 wt.% and 10 wt.%. Several indispensable tests were conducted to investigate the impact of the added cutting on the rheological properties, filtration performance, filter cake properties, and other primary properties such as the drilling fluid density and pH. The results exhibited that the fluctuation of fluid properties was governed by two factors, one was the cutting concertation and the other was the clay content. Filter cake thickness showed high sensitivity at the low cutting concentration while the other properties were mostly in the acceptable range. On the other hand, at higher concentration, the results fall down into two clusters: cuttings with clay content ranging from 0 to 50% (quartz sandstone cuttings, Argillaceous sandstone, and Siliceous claystone) and cuttings with clay content higher than 50% (Kaolinitic claystone) as shown in details in the result section of this work. This works highlight the important of considering the cutting impact on the drilling fluid properties which ultimately impact the whole drilling operations.

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Nonaqueous, Nondamaging Fluid Implemented Offshore Abu Dhabi
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  • Research Article
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Influence of Clay Content and Surfactant on the Rheology of Non Aqueous Drilling Fluids
  • Jun 1, 2014
  • Materials Science Forum
  • Suylan Lourdes Araújo Dantas + 4 more

Organophilic clays are widely used in non-aqueousdrilling fluids, mixtures of different components being used in a well bore. As bentonite claysare not naturally organophilic, they can be modified by specific treatments with surfactants (ionic or nonionic). Recent studies demonstrate the influence of clay, surfactant,and the presence of a dispersant in the rheology of fluids. In this study we verified the influence of clay, and surfactant in the production of organophilic clays using an alcoholic route for the rheology of non-aqueous fluids.As such, we performed the characterization of organophilic clays by X-ray diffraction (XRD),these non-aqueous fluids were produced according to Petrobras norms for rheological testing. The results evidenced influences of the clay / surfactant ratio on the rheology of non-aqueous drilling fluids.

  • Conference Article
  • Cite Count Icon 3
  • 10.4043/24292-ms
Successful Cement Plug in HPHT Pre-Salt Offshore Well in Brazil
  • Oct 29, 2013
  • Gunnar Gerard De Bruijn + 5 more

Industry successful cases and lessons learned have shown the challenges of setting cement plugs in open hole. Using industry best practices, it is possible to successfully set cement plugs in deepwater HPHT wells drilled with non-aqueous fluids. However, it is not uncommon to see cases where a single cement plug job has to be repeated more than once in order to achieve a competent barrier. Among different reasons that would cause a cement plug to fail, are: contamination with non-aqueous drilling fluid, insufficient cement and spacer volumes, density hierarchy, friction pressure hierarchy and cement plug slumping. These challenges become more critical as offshore drilling moves towards new frontiers: deepwater, salt formations, deeper measured depth reaching higher bottom hole temperatures and pressures. In Brazil, drilling operators do not face one single challenge in their operations; they are facing a combination of them in most of the new wells. A successful case will be discussed, which describes the placement of a cement plug isolating an over-pressured gas reservoir and allowing the plug and abandonment operation to continue on a HPHT pre-salt offshore well in Santos Basin, in Brazil. The bottom hole pressure was over 137.8 MPa [20,000 psi] (ultra-high pressure well) and bottom hole temperature 171 degC [340 degF], required 2300 kg/m3 [19.2 lbm/gal] mud weight to maintain the well overbalanced after a gas influx happened when the mud had only a density of 2230 kg/m3 [18.6 lbm/gal]. In addition, the heavy-weight and non-aqueous fluid (NAF) added an extra challenge to this operation. On this case, high density, high performance system (HDHPS) with engineered particle size distribution (PSD) was the selected cement slurry in order to overcome ultra-high formation pressure. Special chemistry was combined to the HDHPS to place the cement plug across the gas reservoir and salt formation, maintaining its stability and assuring isolation of the gas in the reservoir. The cement plug placement was designed with dedicated cement plug placement software, which brought a superior value in analyzing the risks involved, determining the placement technique and confirming best practices, thus aiding to define the pre-job conditions and consequently assuring the success of the P&A. These practices can be successfully extended to other operators plugging and abandoning their wells in deepwater, HPHT wells and even in conventional environments. Introduction Placing cement plugs for sidetrack, remedial work, temporary or permanent abandonment is the highest cement activity offshore. It presents many challenges, including well cleaning, mud removal, minimizing contamination, cement slurry slumping, wait-on-cement sufficient time and more (Bogaerts et al. 2012). By adding to this condition a high pressure reservoir with high density drilling fluid to control the well and maintain it overbalanced, a set of new challenges are introduced to the cement job design and execution. In the following paragraphs the reader will understand why HPHT offshore wells present new challenges for placing successful cement plugs, as well see a thorough discussion on the design, execution and evaluation (DEE) on setting the first cement plug, responsible for isolating the gas reservoir, in the plug and abandonment (P&A) operations of the well 1-OGX-63-SPS drilled in Santos Basin, offshore Brazil.

  • Research Article
  • Cite Count Icon 1
  • 10.2118/1118-0071-jpt
Technology Focus: Drilling and Completion Fluids (November 2018)
  • Nov 1, 2018
  • Journal of Petroleum Technology
  • Trent Jacobs

Technology Focus It is no secret that drilling fluid is crucial in drilling operations. The main function of drilling fluids is to transport drill cuttings from the bottom of the hole up to the surface. Drill cuttings then will be separated on the surface before the fluid is recycled for further drilling. This is to ensure a smooth drilling operation. A drilling-fluids rheological study is a must when drilling a well. Mud engineers and drilling engineers work hand-in-hand to ensure the desired drilling fluid with the right rheological properties is achieved on the basis of reservoir requirements and conditions such as reservoir pore pressure and temperature. Numerous additives are included in drilling fluids to fine-tune the drilling-fluid properties. Such additives include barites for weighting, lime, caustic soda, soda ash, and bicarbonate of soda, as well as other common acids and bases for pH control, amine- or phosphate-based products, and other specially formulated chemicals for corrosion control. In addition, nanofluid also has been introduced to drilling fluid to improve drilling-fluid rheological properties further. Some researchers have worked on nanofluids-enhanced water-based mud prepared using the nanofluids of copper oxide and zinc oxide (sizes of less than 50 nm) in a xanthan-gum aqueous solution as a base fluid. The formulated drilling fluid showed improved thermal and electrical properties by approximately 35% compared with conventional water-based mud. Furthermore, numerous researchers also have studied the application of graphene in drilling fluids. The addition of graphene in drilling fluids improves drilling-fluid properties, specifically with regard to fluid filtration. Graphene-based drilling fluid seems to produce thin, firm, and impermeable mudcake. This, in turn, minimizes the invasion of fluid from wellbore to reservoir rock and minimizes formation damage. Graphene, however, is an expensive additive; 50 g of graphene is approximately $250. Thus, the real challenge is to source graphene from “unwanted” graphite-related waste. In this column, I have highlighted three papers with different novel ideas. One paper discusses the use of a novel polymer over conventional clay as a viscosifier and filtration-control agent. Another paper presents the lesson learned from high-temperature water-based mud offshore Sarawak. The last paper discusses a novel modified rectorite that provides reliable rheology and suspendabilty for biodiesel-based drilling fluids. I hope you enjoy and benefit from the selected and highlighted papers. Other interesting papers are on the recommended additional reading list and in the OnePetro online library. Recommended additional reading at OnePetro: www.onepetro.org. SPE/IADC 189344 Drilling Fluids Automix by Vidar Hestad, Cameron, et al. SPE 186233 Design and Application of Aerated and Foam Drilling Fluid, Case Study in Drilling Operations in Indonesia by WA Nugroho, Pertamina, et al. SPE 187135 Dry Liquids on Silica as Secondary Emulsifiers for Drilling-Mud Applications by V. Lifton, Evonik, et al.

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