Abstract
Reaction of medium caking Illinois No. 6 and highly caking Kentucky HVB coals under mild Friedel-Crafts alkylation conditions rendered the product non-caking. Use of aluminium chloride alone with coal did not change the caking property, while this catalyst in the presence of either an alkyl chloride or benzene did suppress caking. Gaseous HCl decreased but did not eliminate agglomeration. Alkylation of a non-caking Western subbituminous coal had no effect on its non-caking property.
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