Abstract

The emission spectra and the plasma parameters of discharges were investigated. Water solutions of copper and nickel chlorides with additions of sodium chloride were used as electrolyte cathodes. The change of the relative intensities of the emission lines of the elements (Cu and Ni) with increasing NaCl concentrations in the solution is shown. The gas temperature and the reduced electric field strength in the plasma were founded. The electron energy distribution function and the excitation rate coefficients for emitting states of copper and nickel atoms by the numerical solution of the Boltzmann equation were obtained. It was shown that in plasma emission spectroscopy measuring it is necessaryto considerthe correlation between rates of excitation and composition of the sample solution in order to determine the concentration of metal ions in the water solutions.

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