Abstract
The structure of barium nitrate crystals grown from supersaturated aqueous solutions under normal conditions and during centrifugation at 11.8×103g is studied for the first time by a high-precision powder neutron diffraction method. It is established for the first time that centrifuging leads to displacement of the nitrate oxygen atoms in the xy plane (resulting in rotation of the NO3 trigonal prism about the third-order axis) and to variation of the bond lengths and angles in the coordination polyhedron of Ba atoms. The latter changes result in the appearance of a torsional mode in the phonon spectrum of barium nitrate and in increasing stiffness of the crystal lattice, as evidenced by a significant increase in microhardness of the samples grown in the centrifuge.
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