Effect of CdSe/ZnS quantum dot dispersion on phase transitional behavior of 8OCB liquid crystal.

Abstract

We report the effect on the phase transitional behavior of 8OCB liquid crystal (LC) doped with functionalized CdSe/ZnS quantum dots (QDs) in different concentrations. The temperature-dependent data of high-resolution optical birefringence and dielectric anisotropy are utilized to characterize the critical anomaly for both the isotropic-to-nematic (I-N) and nematic-to-smectic-A (N-SmA) phase transitions. The obtained results reveal that the order parameter exponent (β) for the pure LC is found to be β=0.249 and does not vary upon the inclusion of QDs in the pure matrix. It describes the weakly first-order characteristic of the I-N phase transition for all the studied samples, which falls within the limit of the tricritical hypothesis. Conversely, depending on the range of the N phase, we observed a nonuniversal nature of the specific heat capacity critical exponent (α^{'}) linked with the N-SmA phase transition for all the studied samples. A relative comparison was made amongst the α^{'} values extracted from both the anisotropy data, and further, a theoretical relationship is established with these exponent values. The coupling strength among the N and SmA order parameters is determined using the optical birefringence data and discussed from the perspective of mutual interaction between the LC-QDs ligands. The results signify that a strong ligand-ligand interaction between neighboring QDs effectively reduces the N range and slightly influences the N-SmA phase transition.