Abstract
Green synthesis of manganese oxide nanoparticles (NPs) was carried out by sol-gel method using Acacia Concinna fruit extract for removal of reactive dye. The effect of calcination temperature on its morphology was investigated. α-MnO2 and Mn3O4 NPs were synthesized at 400 °C and 900 °C respectively and were characterized by PXRD, SEM, TEM, FTIR, BET, Raman and TGA. As-synthesized MnO2 NPs were investigated for the adsorption of Reactive Blue 21 (RB-21) dye. The effect of pH, adsorbent dose, agitation speed, initial dye concentration and temperature on dye removal was explored. pHpzc was calculated from zeta potential study showing positive surface charge below pH 3.18 resulting in electrostatic force of attraction between adsorbate and adsorbent. Both linear and non-linear regression approaches were utilised for the fitting of kinetic models and adsorption isotherms. Adsorption data follows a pseudo second order kinetics and fits well with the Freundlich isotherm model. Thermodynamic parameters such as ΔHo, ΔSo and ΔGo were determined. The dye removal efficiency, in case of MnO2 NPs at pH 3.0 was obtained to be 98% whereas for Mn3O4, no such dye adsorption was observed. The mechanism of adsorption was studied theoretically confirming π-π interaction and H-bonding between the MnO2 and RB dye molecules.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
