Abstract
Electrochemical electrodes comprise multiple phenomena at different scales. Several works have tried to model such phenomena using statistical techniques. This paper proposes a novel process to work with reduced size images to reconstruct microstructures with the Simulated Annealing method. Later, using the Finite Volume Method, it is verified the effect of the image resolution on the effective transport coefficient (ETC). The method can be applied to synthetic images or images from the Scanning Electron Microscope. The first stage consists of obtaining the image of minimum size, which contains at least 98% of the statistical information of the original image, allowing an equivalent statistical study. The image size reduction was made by applying an iterative decimation over the image using the normalized coarseness to compare the amount of information contained at each step. Representative improvements, especially in processing time, are achieved by reducing the size of the reconstructed microstructures without affecting their statistical behavior. The process ends computing the conduction efficiency from the microstructures. The simulation results, obtained from two kinds of images from different materials, demonstrate the effectivity of the proposed approach. It is important to remark that the controlled decimation allows a reduction of the processor and memory use during the reconstruction and ETC computation of electrodes.
Highlights
Electrodes are essential in fuel cells to produce electrical energy
Each 2D material is reconstructed to obtain a ω realization of a Ω ensemble of ten different random
This paper presents a new methodology for random heterogeneous material (RHM) reconstruction to obtain the conduction efficiency in two-phase materials
Summary
Electrodes are essential in fuel cells to produce electrical energy. The design of electrochemical electrodes requires that models consider multiple phenomena at different scales. This is the case of a proton exchange membrane fuel cell (PEMFC) electrode [1]. While the catalyst has the role of promoting the proper electrochemical reactions, the carbon collects and conducts the produced electrons, and the ionomer should conduct protons. Materials 2019, 12, 3757 generated or consumed by the proper reaction. At the microscale, the PEMFC electrode can be modeled by agglomerates in a porous matrix [3], in this scale, a Scanning Electron Microscope (SEM) produces high-resolution images of the microscopic structure
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.