Abstract
Passivity of carbon steel was examined in saturated Ca(OH)2 solution with different alternating temperatures. The results showed that the Fe3+/Fe2+ and OH-/O2- ratios decreased, and donor density in the passive film increased with the amplitude of temperature alternation. Cracks were observed in the film when the sample experienced a higher amplitude of temperature change. Passive films on the samples in 20–50 °C and 20–60 °C alternating temperature solution were less stable than those of their counterparts in 40 °C and 50 °C solution, respectively. Furthermore, a model was proposed to explain the degradation of passive films under alternating temperature.
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