Effect of activator concentration on setting time, workability and compressive strength of sustainable concrete with alkali-activated slag binder

Abstract

The global need to reduce carbon dioxide (CO2) emissions prompted studies on sustainable alternatives to conventional concrete made with ordinary Portland cement (OPC) binders. Alkali-activated ground granulated blast furnace slag (GGBS) is a promising sustainable to OPC in terms of the impact on the environment and reduction of CO2 emissions. Concretes and mortars made with alkali-activated binders demonstrate promising fresh and mechanical properties. This article presents the findings of an experimental study investigating the fresh and mechanical properties of mortar using alkali-activated GGBS binder. The activators used were sodium silicate (Na2SiO3) and sodium hydroxide (NaOH) solution with 6 M, 8 M, 10 M, and 12 M molarities. The study assessed their initial setting time, workability, and 28-day compressive strength. The study evaluated the effect of partial replacement of GGBS with 5 % silica fume. The compressive strength was determined after 28 days of curing in three different environments: 1) ambient air temperature, 2) water submersion, and 3) water immersion for 7 days followed by 21 air curing in ambient temperature. The results showed an increase in compressive strength with higher NaOH concentration but a corresponding decrease in initial setting time and flowability. Depending on the curing method, efflorescence, and blue-green pigmentation were seen during the physical assessment of the samples. The highest 28-day compressive strength was 67.5 MPa when the NaOH activator molarity was 10 mol/L which represents an optimum concentration for strength development. Replacing 5 % of the GGBS binder with silica fume resulted in a decrease in the 28-day compressive strength and workability without affecting the initial setting time.