EDTAD-modified cassava stalks loaded with Fe3O4: highly efficient removal of Pb2+ and Zn2+ from aqueous solution.

Abstract

In this study, a novel magnetic cassava stalk composite (M-EMCS) was prepared through modification with ethylenediamine tetraacetic anhydride (EDTAD) and loading of Fe3O4. The surface morphology, molecular structure, and magnetic characteristics of the composite were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), vibrating-sample magnetometer (VSM), and X-ray diffraction (XRD). It was shown that EDTAD and Fe3O4 were successfully modified and loaded in cassava straw (CS), respectively. The capacity of M-EMCS to absorb heavy metals under different influencing factors was tested by atomic absorption spectroscopy. The adsorption processes of both Pb2+ and Zn2+ were suitably described by second-order kinetic models and Langmuir models, indicating monolayer chemisorption. M-EMCS had high adsorption rates and adsorption capacities for these two metal ions. The adsorption of Pb2+ and Zn2+ reached a plateau after 10min, and the adsorption capacity of Pb2+ (163.93mg/g) was higher than that of Zn2+ (84.74mg/g). Thermodynamic analysis showed that the adsorption of two metals by M-EMCS was spontaneous, endothermic, and irreversible. XPS analysis showed that M-EMCS mainly removes Pb2+ and Zn2+ through ion exchange, chelation, and redox. Graphical abstract.