Abstract
The structure and dynamic behavior of complex [(η 5-C 5H 4CH 3)Cr(CO) 2(μ-SBu)Pt(PPh 3) 2] in solution was studied by multinuclear ( 1H, 13C, 31P) NMR spectroscopy including a phase-sensitive NOESY experiment. Increasing temperature causes rupture of the Cr–Pt bond in the three-membered ring of the complex and rotation of the S–Pt(PPh 3) 2 unit around the Cr–S bond line, followed by formation of a new Cr–Pt bond to close the ring. All activation parameters for this dynamic process have been determined.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
