Abstract
Trivalent-doped tetragonal xenotime yttrium orthophosphate phosphors have attracted significant attention as promising materials for deep ultraviolet (DUV) luminescence. In this study, we achieved DUV electroluminescence (EL) using Bi3+-doped bi-phase yttrium phosphate (YPB) phosphor under an AC-driven sinusoidal waveform. Phosphor powder was synthesized via a solid-state reaction with an optimal Bi3+ concentration. The phosphor exhibited a mixed phase of xenotime tetragonal YPO4 and monoclinic Y(PO3). We suggest that the mixed phase within the phosphor particles plays a crucial role in enhancing light generation via a bipolar field emission mechanism in the developed powder-based EL device. It emitted a narrow-band DUV emission spectrum peaking at 243 nm, which was attributed to the 3P1 → 1S0 transition of the Bi3+ ions within the mixed host lattices. Moreover, it has a lower voltage application than the excimer lamp DUV sources. The application of the YPB phosphor in EL devices presents an appealing outlook for future advancements in the development of DUV sources.
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