Abstract
Front Cover: In article number 1800627 by Marco Sangermano, Frank Wiesbrock, and co-workers, bicyclic spiroorthoesters undergo volumetric expansion upon cationic (double) ring-opening polymerization. They can be used as additives in polymerizations to control the shrinkage that conventional polymerizations exhibit; if the spiroorthoesters bear olefinic structural motifs, they can be covalently attached into thiol–ene networks, while the shrinkage/expansion can be tailored.
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