Abstract
The theory of the generalized mean amplitudes of vibration has been applied to the C3S2 molecule, which possesses a linear symmetrical structure. The numerical values of the force constants and the mean square parallel and perpendicular amplitudes at 298°K of all bonded and non-bonded pairs of atoms are calculated from spectroscopic vibrational frequencies by the Cyvin and Morino–Hirota methods, utilizing the symmetry coordinates. The "shrinkage" effect constants are also evaluated by means of the perpendicular mean square amplitudes.
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