Abstract
Foams have recently been characterised as ideal products for pharmaceutical and topical use applications for the delivery of topical active agents. Foams are usually produced in a wet form but in a number of applications moderately dry foams are required. Drying of foam under terrestrial conditions proceeds under the action of gravity, which is impossible under microgravity condition. Below a new method of drying foams under microgravity condition is suggested. According to this method foam should be placed on a porous support, which will absorb the liquid from foam based on capillary forces only. The final liquid content inside the foam can be achieved by a proper selection of the porous support. The suggested method allows drying foams under microgravity conditions. Interaction of foams with porous support under terrestrial conditions was developed only recently and theoretically investigated (Arjmandi-Tash, O.; Kovalchuk, N.; Trybala, A.; Starov, V. Foam Drainage Placed on a Porous Substrate. Soft Matter2015, 11 (18), 3643–3652) followed by a theory of foam drainage on thin porous substrates (Koursari, N.; Arjmandi-Tash, O.; Johnson, P.; Trybala, A.; Starov, M. V. Foam Drainage Placed on Thin Porous Substrate. Soft Matter, 2019, (submitted)), where rate of drainage, radius of the wetted area inside the porous layer and other characteristics of the process were predicted. The latter model is modified below to investigate foam drying under microgravity conditions. Model predictions are compared with experimental observations for foam created using Triton X-100 at concentrations above CMC. Wetted radius inside the porous substrate was measured and results were compered to model predictions. Experimental observations for spreading area versus time show reasonable agreement with theoretical predictions for all investigated systems.
Highlights
Foam is a colloidal dispersion where gas bubbles are dispersed in a continuous liquid phase
The suggested method of drying foam at microgravity conditions is applicable at any liquid volume fraction below ~35%
We consider moderately dry foams with initial liquid volume fraction below 12% and include all liquid into Plateau borders (PB), that is the whole liquid is concentrated inside the PBs
Summary
Foam is a colloidal dispersion where gas bubbles are dispersed in a continuous liquid phase. We consider moderately dry foams with initial liquid volume fraction below 12% and include all liquid into Plateau borders (PB), that is the whole liquid is concentrated inside the PBs. Estimations below (see Eq (4)) based on calculations by (Wang Narsimhan 2006) show that the influence of surface viscosity can be neglected and no-slip boundary conditions can be adopted on the PB surfaces. The flow inside the foam is assumed to occur inside the Plateau regions only and the contribution of the liquid flow in the films and nodes is neglected In this case the drainage kinetics can be described by the following equation Equation (18) shows that it is possible to control the final liquid contents inside the foam by varying the
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