Abstract

AbstractDry polymer electrolytes are a promising class of materials for future safer high‐energy‐density battery technologies. This review deals with the relevant physico‐chemical properties of the dry polymer electrolytes, ionic transport mechanism, molecular structure, and interfacial issues in a widely investigated model system (poly(ethylene oxide) with lithium bis(trifluoromethanesulfonyl)imide). At the end of the review, latest macromolecular approaches for high‐performance lithium battery applications are discussed.

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