Abstract

Double photoionization of N2into the N22+D1Σu+-stateas a function of the exciting-photon energy has been investigated experimentally andtheoretically. Photon-induced fluorescence spectroscopy using monochromatizedsynchrotron radiation in the exciting-photon energy range between 50 and 66.5 eVand recording of the intensity of the dispersed VUV fluorescence between 145 and167 nm has been carried out. Relative cross sections as a function of theexciting-photon energy have been determined. The experimental results arecompared with ab initio calculations.

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