Abstract
Not only AuAu but also RhAu interactions are responsible for the unusual trigonal-pyramidal coordination of the oxygen atoms in the complex cation 1. The picture on the right shows the Au4Rh2O2 core of the cluster with norbornadiene (nbd) ligands at the Rh centers; the phosphane ligands have been omitted. The synthesis of this novel heteronuclear cluster is relatively simple. [{(nbd)Rh[μ-O(AuPPh3)2]}2]2+ 1
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