Abstract

AbstractDimethyl acetylenedicarboxylate reacts with 2 mol‐equiv. B(C6F5)3 by C6F5 transfer to the central acetylenic C≡C bond with formation of a tail‐to‐tail coupled bis(boron ester enolate) system. The central hexasubstituted butadiene unit of this unique system reacts with dimethyl maleate in a Diels–Alder reaction to give a hydroquinone derivative.

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