Abstract
It was shown that pattern of domain structure in ferroic crystals undergoing a sequence of phase transitions, changes and depends on the phase preceding the phase with ferroic arrangement. Two crystals were taken into considerations: β-L1NH4SO4 and (NH4)3H(SeO4)2. The orientation of domain walls, both ferroelectric and ferroelastic, is determined by random domain walls, which appeared in the previous phase both ferroelectric and ferroelastic, or a regular large scale structure, which was found in the vicinity of phase transition in β-LiNH4SO4.
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