Distribution of Policyclic aromatic hydrocarbons in a snow cover in the territory of Ivanovo city, Russia.

Abstract

The paper presents the results of a study of the content of 12 polyaromatic hydrocarbons (PAHs) in the snow cover of the city of Ivanovo (Russian Federation). It is shown that their average content exceeds the background level by 6.6 times, which made it possible to identify for which compounds the admission channels are associated with transboundary transport (naphthalene, pyrene, benz [b]fluorantin, benzo [a]pyrene and dibenz [a,h]anthracene), and for which with local emission sources (anthracene, phenanthrene, fluoranthene, chrysene, benz [k]fluorantin, and benzo [g,h,i]perylene). According to the known indicator ratios of the concentrations of PAHs, the main sources of release (pyrogenic and mixed) PAHs into the environment were estimated. The combination of experimental data in combination with factor analysis allowed identifying priority PAHs (naphthalene, fluoren, fluoranthene, benzo [a]pyrene and benzo [g,h,i]perylene), which should be included in the environmental monitoring programs of the region. Environmental risk assessments are given, which showed that the level of pollutant does not always adequately reflect the environmental impact for the territories. Thus, the contribution to the total PAH concentration of benz [b]fluorantin is only 9%, and to the amount of environmental risk - 51%. This must be taken into account in order to prioritize the control of individual components of PAHs in environmental objects.