Dissolved organic matter (DOM) was detected in MSWI plant: An investigation of DOM and potential toxic elements variation in the bottom ash and fly ash

Abstract

The content of dissolved organic matter (DOM) and potentially toxic elements (PTEs) were investigated in the bottom ash (BA) and fly ash (FA) of different sections of the municipal solid waste incineration (MSWI) plant. BA and FA were collected from the dry (BA1-BA2), burn (BA3-BA4), and burn-out (BA5) sections of the grate incinerator; FA was collected after denitration (DNFA), and from the deacidification tower (FA1) and bag-type dust remover (FA2), respectively. The DOM concentration in BA was higher than that in FA, the highest concentration was in BA3 (556.18 mg/kg), while the lowest concentration was in DNFA (17.53 mg/kg). DOM in BA was mainly composed of protein-like, fulvic-like, tryptophan-like, and humic-like substances, of which humic-like substances accounted for more than 40%. DOM in FA consisted of tryptophan-like and humic-like substances, of which humic-like substances accounted for more than 80%. DOM still existed in BA which may be related to the incomplete combustion, and the influence of microbes, while DOM was increased in FA1, which might be due to the addition of lime slurry. PTEs were analyzed by the Tessier extraction method, Fe-Mn hydroxide-bound fraction of PTEs increased in FA1 in which DOM concentration (137.22 mg/kg) was 7.83 times that in DNFA. The increase of DOM may lead to a higher risk of PTEs in FA. FTIR results indicated that DOM can bond to PTEs in BA and FA. The contents of humus-like substances in DOM were positively correlated with the effective fraction of As, Cu, Pb, Cr, and Cd. This paper investigated the risk of DOM existing in BA and FA in MSWI plant, which can provide a new perspective on how to deal with BA and FA, and reduce their environmental risks.