Abstract
Abstract Several authors determined dissociation constants of acids such as benzoic, succinic and azelaic acids in mixed solvents and reported that the dissociation constants determined in aqueous dioxane were higher than those determined in aqueous alcohols having the same dielectric constants. However, if the variation of the amount of water in mixed solvents is taken into consideration in calculating the dissociation constant, an acid has almost the same dissociation constant in various mixed solvents with the same dielectric constant.
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