Dissipation dynamics of fenoxaprop-p-ethyl and fenoxaprop acid under Indian rice field conditions

Abstract

ABSTRACTDissipation dynamics of fenoxaprop-p-ethyl (FPPE) and fenoxaprop acid (FPA) (metabolite) in rice field conditions was investigated for two consecutive seasons. FPPE dissipated rapidly in soil with average half life of 1.42–2.19 days. Dissipation followed first-order kinetics. The method was validated in terms of accuracy, linearity, specificity and precision. Linearity was in the range of 0.005–5 µg mL−1 with limit of detection as 0.002 and 0.001 µg mL−1 for fenoxaprop-p-ethyl and fenoxaprop acid, respectively. Quantitation limit in soil, grain, straw and husk were 0.005, 0.008, 0.01 and 0.01 µg g−1 for fenoxaprop-p-ethyl, and 0.005, 0.01, 0.01 and 0.01 µg g−1 for fenoxaprop acid, respectively. Recovery in soil, rice grains, straw and husk ranged from 81.60–93.40, 77.85–87.00, 75.20–84.40 and 76.00–87.20% for FPPE and 82.50–88.20, 76.25–83.00, 74.80–83.60 and 75.00–85.40% for FPA, respectively. Below detectable limit of residues of FPPE and metabolite were observed in soil, rice grain, husk and straw samples at harvest. FPPE and FPA were of short persistence under field conditions and residues were below European Union-Maximum Residue Limits in all matrices that would cause adverse effect on environment and human/animal health.