Abstract
After the direct metalation of free base porphyrins (2HTPP, 2HTTBPP) with different metal atoms was demonstrated successfully ( Chaps. 6 and 7), analogue experiments were performed with an ordered monolayer of free base phthalocyanine (2HPc) on a silver (111) surface. 2HPc reacts with the stoichiometric amount of co-adsorbed Fe atoms to form iron(II)-phthalocyanine [Fe(II)Pc]. The formation of Fe(II)Pc was confirmed by comparison with the directly deposited complex using STM. No side reactions such as the coordination of Fe atoms on the peripheral nitrogen atoms of the phthalocyanine molecules were observed.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
