Abstract

The present study deals with the use of liquid secondary ion mass spectrometry in combination with collisionally activated dissociation and linked scanning at constant B/E for differentiation and structural analysis of 6-C- and 8-C-glycosidic flavonoids in the positive ion mode. Flavonoids of mono-C-glycosidic nature were investigated. Special emphasis is given to the rationalization of fragment ions which allow differentiation between isomers.

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