Abstract
(Dicyclopentadiene) platinum(II) dichloride was found to be an efficient hydrosilylation catalyst (homogeneous) upon a wide variety of functionalized alkenes and alkenes terminated with chemical moieties (diphenyl amino-, N-carbazol- and N-isoindoline-1,3-dione-). It is noteworthy that the hydrosilylation of aminated alkenes with triethoxysilane exhibited the yield of over 70% and the selectivity (γ-isomer/β-isomer) of more than 3/1. Due to steric hindrance lowering Markovnikov probability, the alkenes with big terminal moieties (diphenyl amino-, N-carbazol- and N-isoindoline-1,3-dione-) presented the high ratio of anti-Markovnikov isomers. The strategy of the hydrosilylation of the protected diamino chelating alkene was developed.
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