Abstract
In the title complex, [PdBr2(C12H8N2)], the PdII ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two bromide ions. The complex displays numerous intermolecular π–π interactions between adjacent six-membered rings, the shortest centroid–centroid distance being 3.680 (4) Å. The nearly planar [maximum deviation 0.143 (2) Å] molecules stack in columns parallel to (101) with a Pd⋯Pd distance of 4.8466 (9) Å.
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