Abstract
A family of aryl dinuclear bismuthane complexes has been successfully synthesized and characterized. The two bismuth centers are bonded to various xanthene-type backbones, which differ in ring-size and flexibility, resulting in complexes with different intramolecular Bi⋯Bi distances. Moreover, their pentavalent Bi(v) analogues have also been prepared and structurally characterized. Finally, the synergy between bismuth centers in catalysis has been studied by applying dinuclear bismuthanes 5–8 to the catalytic oxidative cleavage of 1,2-diols. Unfortunately, no synergistic effects were observed and the catalytic activities of dinuclear bismuthanes and triphenylbismuth are comparable.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.