Abstract
The crystal structure determination of the title compound, [Cu(C4H12N2)2(H2O)2](C4O4), is reported. It adopts an elongated octahedral trans-[CuN4O2] coordination geometry with the CuII atom located at a centre of symmetry. The axial Cu—O bond length is 2.6066 (17) A, while the equatorial Cu—N bond lengths are 1.9849 (16) and 2.1102 (16) A. Intermolecular O—H⋯O and N—H⋯O hydrogen bonds are responsible for linking the complex cation to the squarate dianion, forming layers. The anion is also centrosymmetric.
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