Abstract
A practical method for the construction of chiral molecules has been designed using a novel strategy based on systems possessing multiple metal centers and tartaric acid esters as chiral auxiliaries. By using this design,we have developed methods for carrying out highly enantioselective (1) Simmons-Smith reaction, (2) 1,3-dipolar cycloaddition reactions of nitrile oxides and nitrones, and (3) nucleophilic additions of organometallic compounds to imine derivatives.
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