Development of Membrane Electrode Assemblies for State-of-the-Art Anion Exchange and Proton Exchange Membrane Electrolysis

Abstract

Proton exchange membrane (PEM) electrolysis and anion exchange membrane (AEM) electrolysis are both able to directly produce high purity hydrogen from electricity and water. Key benefits of electrolysis using polymer membrane separators include a quick response rate, enabling load following, and ability to operate with high differential pressure. Operation under differential pressure allows for simultaneous electrolysis and electrochemical compression, simplifying overall system design. The development and stack integration of new, high performance electrolysis materials must include consideration of operating range and durability under differential pressure to maintain the technologic benefits. PEM electrolyzers are commercially available on the megawatt scale and produce hydrogen fuel that is increasingly cost competitive with fossil fuel in select parts of the world. Better utilization of low cost electricity from renewable energy (wind and solar) is one route to additional hydrogen cost reductions, for which a wide current operating range is beneficial. Thinner membranes, more active catalysts, and better electrode design enable high currents at acceptable cell efficiencies. Performance and durability data will be presented on state-of-the-art PEM electrolyzer materials operating under differential pressure. AEM electrolyzers are not currently commercially available, but promise membrane, catalyst, and balance of stack cost reductions. To begin to compete with PEM technology, performance and durability need to be improved. This work focuses on membrane stability under differential cell pressure and material integration into high performance AEM electrolyzers.