Abstract

The unfavourable relationship between electrical and thermal conductivity limits the choice of solid-state materials for thermoelectric generators (TEG). Among ionic liquids (IOL), it appears that a large variety of thermoelectric (TE) materials with promising high Seebeck coefficients have potential for development. Furthermore, the novel solid-on-liquid deposition technology (SOLID) allows the encapsulation of liquid TE materials to create new, highly integrated TEG devices. Following this vision, this paper studies a large number of IOLs looking at TE-relevant parameters such as thermal and electrical conductivity, Seebeck coefficient and temperature-dependent viscosity. We show that positive and negative Seebeck coefficients can be obtained, depending on the molecular structure and the viscosity of the IOL. The properties of single-junction TEGs are presented in terms of I–V characteristics correlated with the IOL properties. We prove that the limiting effect of conversion efficiency is the current density that can be extracted from a device rather than the Seebeck coefficient.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.