Abstract
A new simple techique for the microdetermination of fluorine in the presence of aluminum was obtained by using the fluoride ion electrode. Procedures are as follows ;Aluminum fluoride complexes were deeomosed in alkali (pH>12) and the liberated aluminum was masked with oxine. The pH and total ionic strength were adjusted with TISAB, and fluorine determination was carried out with no extraction of the aluminum-oxine complex and free oxine.The calibration curve showed a linearity down to less than 0.1 ppm (5.3×1O-6M) of fluorine in the presence of 4 ppm of aluminum and oxine, which is as good as measurements obtained in the absence of aluminum.Recovery of 1 ppm of fluorine was relatively good-about 95%-, even in the presence of 200 ppm of aluminum. Good recovery of fluorine added to artificial cryolite was also found.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
