Abstract
In the present work, the derivation of the standard rate constant k0, the transfer coefficient a and the standard (or formal) potential E0 of immobilized electroactive species, with the use of large amplitude Fourier transform alternating current cyclic voltammetry (FTacV) is examined. Both the kinetic equation of the coverage and the current integral equation are solved. The kinetic regions of the current response are distinguished, the chief observables in the case of both fast and slow kinetics are showcased and finally based on these, a methodology to extract k0, a and E0 is introduced.
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