Abstract
The Brønsted acid site was determined by using volumetric and Potentiometrie titration method. The result showed that the Brønsted acid sites of synthesized aluminosilicate using volumetric titration method are aluminosilicate-1: 0.5491; aluminosilicate-2: 0.5523; and aluminosilicate-3: 0.5772 mmol/g and using potentiometric titration method are aluminosilicate-1: 4.7087; aluminosilicate-2: 5.5739; and aluminosilicate-3: 8.1059 mmol/g. FTIR-pyridine also showed the same trend line, the Brønsted acid sites concentration increased by the increasing of Si/Al mole ratio. The results of the measurement using FTIR-pyridine showed the Brønsted acid sites concentration of aluminosilicate-1; aluminosilicate-2; and aluminosilicate-3 were 0.0293; 0.330; and 0.0336 mmol/g, respectively. The Brønsted acid sites concentration of aluminosilicate was higher using volumetric titration and potentiometric titration methods than using the FTIR-pyridine method, but the trend line was the same, the higher Si/Al mole ratio, concentration of Brønsted acid sites increased.
Highlights
The catalysts need for a wide range of organic reactions is currently increasing
The Brønsted acid site was determined by using volumetric and potentiometric titration method
The result showed that the Brønsted acid sites of synthesized aluminosilicate using volumetric titration method are aluminosilicate-1: 0.5491; aluminosilicate-2: 0.5523; and aluminosilicate-3: 0.5772 mmol/g and using potentiometric titration method are aluminosilicate-1: 4.7087; aluminosilicate-2: 5.5739; and aluminosilicate-3: 8.1059 mmol/g
Summary
The catalysts need for a wide range of organic reactions is currently increasing. The type of catalyst which is the first interest nowadays is the heterogeneous catalyst. Series: Earth and Environmental Science 217 (2019) 012002 doi:10.1088/1755-1315/217/1/012002 Determination of Brønsted Acid Sites In Porous Aluminosilicate Solid Catalysts Using Volumetric And Potentiometric Titration Method
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: IOP Conference Series: Earth and Environmental Science
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
