Abstract
An ebulliometric method was examined for determining the vapor–liquid equilibrium on binary systems consisting of close-boiling components. The boiling points of five binary systems were measured (ethylbenzene and m-xylene, o-chlorotoluene and p-chlorotoluene, benzene and cyclohexane, carbon tetrachloride and ethylacetate, and heptane and methylcyclohexane) at the pressure of 40.00–93.32 kPa. The vapor–liquid equilibria were determined by the Wilson equation from the experimental boiling points. In addition, the infinite dilution activity coefficients were calculated from the boiling point and their thermodynamic consistency was checked on the basis of the Gibbs–Helmholtz equation.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.