Abstract
Mathematical models were proposed to clarify the effect of alloying on corrosion of magnesium alloys based on film-free and film-covered status. The models are applicable to explain the “barrier effect” by cathodes and the “analogous Hall-Petch relationship” between corrosion rates and grain size. The slope of corrosion rates versus alloying content is determined by the dissolution ability of film-free substrate and the hindering effects by corrosion product film. Designing strategy for corrosion-resistant Mg alloys is established.
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